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71.
Chun‐Feng Wang Dr. Ren‐Fu Li Prof. Dr. Xue‐Yuan Chen Dr. Rong‐Jia Wei Prof. Dr. Lan‐Sun Zheng Prof. Dr. Jun Tao 《Angewandte Chemie (International ed. in English)》2015,54(5):1574-1577
Hybrid materials integrated with a variety of physical properties, such as spin crossover (SCO) and fluorescence, may show synergetic effects that find applications in many fields. Herein we demonstrate a promising post‐synthetic approach to achieve such materials by grafting fluorophores (1‐pyrenecarboxaldehyde and Rhodamine B) on one‐dimensional SCO FeII structures. The resulting hybrid materials display expected one‐step SCO behavior and fluorescent properties, in particular showing a coupling between the transition temperature of SCO and the temperature where the fluorescent intensity reverses. Consequently, synergetic effect between SCO and fluorescence is incorporated into materials despite different fluorophores. This study provides an effective strategy for the design and development of novel magnetic and optical materials. 相似文献
72.
Dr. Wei‐Wei Xiong Jianwei Miao Dr. Kaiqi Ye Prof. Dr. Yue Wang Prof. Dr. Bin Liu Prof. Dr. Qichun Zhang 《Angewandte Chemie (International ed. in English)》2015,54(2):546-550
Inserting polymers into a crystalline inorganic matrix to understand the structure, position, and the structure–property relationships of the resulting composites is important for designing new inorganic‐organic materials and tuning their properties. Single crystals of polymer‐chalcogenide composites were successfully prepared by trapping polyethyleneglycol within a selenidostannate matrix under surfactant‐thermal conditions. This work might provide a new strategy for preparing novel crystalline polymer‐inorganic composites through encapsulating polymer chains within inorganic matrices. 相似文献
73.
Dr. Silvia Bracco Dr. Mario Beretta Dr. Alice Cattaneo Prof. Angiolina Comotti Prof. Andrea Falqui Dr. Ke Zhao Prof. Charles Rogers Prof. Piero Sozzani 《Angewandte Chemie (International ed. in English)》2015,54(16):4773-4777
New mesoporous covalent frameworks, based on hybrid fluorinated organosilicas, were prepared to realize a periodic architecture of fast molecular rotors containing dynamic dipoles in their structure. The mobile elements, designed on the basis of fluorinated p‐divinylbenzene moieties, were integrated into the robust covalent structure through siloxane bonds, and showed not only the rapid dynamics of the aromatic rings (ca. 108 Hz at 325 K), as detected by solid‐state NMR spectroscopy, but also a dielectric response typical of a fast dipole reorientation under the stimuli of an applied electric field. Furthermore, the mesochannels are open and accessible to diffusing in gas molecules, and rotor mobility could be individually regulated by I2 vapors. The iodine enters the channels of the periodic structure and reacts with the pivotal double bonds of the divinyl‐fluoro‐phenylene rotors, affecting their motion and the dielectric properties. 相似文献
74.
A Family of Molecular Sieves Containing Framework‐Bound Organic Structure‐Directing Agents 下载免费PDF全文
Jun Kyu Lee Dr. Jiho Shin Nak Ho Ahn Alessandro Turrina Dr. Min Bum Park Dr. Youngchul Byun Prof. Sung June Cho Prof. Paul A. Wright Prof. Suk Bong Hong 《Angewandte Chemie (International ed. in English)》2015,54(38):11097-11101
Organic structure‐directing agents (OSDAs), such as quaternary ammonium cations and amines, used in the synthesis of zeolites and related crystalline microporous oxides usually end up entrapped inside the void spaces of the crystallized inorganic host lattice. But none of them is known to form direct chemical bonds to the framework of these industrially important catalysts and adsorbents. We demonstrate that ECR‐40, currently regarded as a typical silicoaluminophosphate molecular sieve, constitutes instead a new family of inorganic‐organic hybrid networks in which the OSDAs are covalently bonded to the inorganic framework. ECR‐40 crystallization begins with the formation of an Al–OSDA complex in the liquid phase in which the Al is octahedrally coordinated. This unit is incorporated in the crystallizing ECR‐40. Subsequent removal of framework‐bound OSDAs generates Al‐O‐Al linkages in a fully tetrahedrally coordinated framework. 相似文献
75.
Genta Kawaguchi Prof. Dr. Mitsuhiko Maesato Dr. Tokutaro Komatsu Prof. Dr. Hiroshi Kitagawa Prof. Dr. Tatsuro Imakubo Dr. Andhika Kiswandhi Dr. David Graf Prof. Dr. James S. Brooks 《Angewandte Chemie (International ed. in English)》2015,54(35):10169-10172
Simultaneous manipulation of both spin and charge is a crucial issue in magnetic conductors. We report on a strong correlation between magnetism and conductivity in the iodine‐bonded molecular conductor (DIETSe)2FeBr2Cl2 [DIETSe=diiodo(ethylenedithio)tetraselenafulvalene], which is the first molecular conductor showing a large hysteresis in both magnetic moment and magnetoresistance associated with a spin‐flop transition. Utilizing a mixed‐anion approach and iodine bonding interactions, we tailored a molecular conductor with random exchange interactions exhibiting unforeseen physical properties. 相似文献
76.
Realizing both High Energy and High Power Densities by Twisting Three Carbon‐Nanotube‐Based Hybrid Fibers 下载免费PDF全文
Ye Zhang Yang Zhao Dr. Xunliang Cheng Dr. Wei Weng Jing Ren Xin Fang Yishu Jiang Peining Chen Zhitao Zhang Prof. Yonggang Wang Prof. Huisheng Peng 《Angewandte Chemie (International ed. in English)》2015,54(38):11177-11182
Energy storage devices, such as lithium‐ion batteries and supercapacitors, are required for the modern electronics. However, the intrinsic characteristics of low power densities in batteries and low energy densities in supercapacitors have limited their applications. How to simultaneously realize high energy and power densities in one device remains a challenge. Herein a fiber‐shaped hybrid energy‐storage device (FESD) formed by twisting three carbon nanotube hybrid fibers demonstrates both high energy and power densities. For the FESD, the energy density (50 mWh cm?3 or 90 Wh kg?1) many times higher than for other forms of supercapacitors and approximately 3 times that of thin‐film batteries; the power density (1 W cm?3 or 5970 W kg?1) is approximately 140 times of thin‐film lithium‐ion battery. The FESD is flexible, weaveable and wearable, which offers promising advantages in the modern electronics. 相似文献
77.
本文讨论了高次杂交壳体元在材料非线性分析中的应用,为了更精确估计单元内各部分应力的不同影响,本文应用了分区非线性变分原理推导出杂交壳元在应力增量下应用初始应力法的失衡节点力,这使得高次杂交元在非线性分析中的优点得以充分的发挥,从而大大提高了计算精度。 相似文献
78.
本文应用混合型有限元双向分配法得到有侧移刚架的数值解。文中给出了计算机程序,具有占用内存少、收敛快等特点。文末给出了算例。 相似文献
79.
本文基于一个改进的弹塑性的Hellinger/Reis■ner 混合变分原理构造了一种用于解弹塑性问题的四节点等参杂交应力元.新的模型中,在单元内增加了等效应力增量、塑性等效应变增量及不协调位移变量,从而使单元内的屈服准则及流动法则平均得到满足,不协调位移改进了单元应力精度.计算表明,新的模型可以提高弹塑性杂交法的精度和计算效率. 相似文献
80.
采用解析和数值方法研究FRP-混凝土杂交梁的界面应力问题。提出了杂交梁的新的力学模型和假设,克服了以往的分析模型中界面应力表达式非常复杂和界面应力的解析解与数值解相差较大的缺点,本文得到的FRP板加固梁的界面剪应力表达式与数值结果符合很好,并且具有简捷的表达式。利用有限元法研究了杂交梁各物理参数对界面剪应力的影响。研究表明,界面剪应力在FRP板的端部存在应力集中或应力奇性,这是造成杂交梁界面破坏的主要原因。这项研究对进行杂交结构的工程设计具有理论指导和参考价值。 相似文献